Recently, Gouygou et al. [25, 26] have reported the reactivity of epoxides derived from the sesquiterpenic himachalenes in the presence of Lewis filexlib. We report a new pathway of epoxide formation in organic phases via catalytic aqueous-phase ring-opening reactions, especially in acidic
PDF | tert-Butylimidochromium complexes catalysed ring opening of epoxides by SiMe3(N3) to give azidohydrins in good yields. The proposed mechanism for.
Figure 1 shows the FTIR spectra of the cationic/radical initiated resin systems with different contents of epoxy under UV irradiation by a desk 3D printer with
Nucleophilic Ring-Opening Reactions of.With no labile hydrogens, ethers have no acidic hydrogens to abstract. ethers epoxides and sulfides problems. Due to the
The hydride-terminated polysiloxanes were then functionalized with glycidyl epoxide or aliphatic amine groups via hydrosilation reactions. The aim of this project was to measure the rate coefficients of the reactions between peroxy radicals and unsaturated compounds at room temperature by
(17) For an acetyl transfer reaction originating from a vitamin K hydro- peroxide analogue, see: Wilson, R. M.; Tharp, G. J. Am. Chem. Soc. 1985,. 107, 4100. (
These moieties either originate from GLYDA itself, or form as a result of epoxy-acid reaction. The DLP cured objects are subsequently subjected
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